Roon supports grouped playback on audio-only Chromecast devices via the Google Home app. Using the Google Home app, you can set up groups of devices, which then appear as additional audio devices in Roon alongside the hardware devices. So for example, you could group a few Chromecasts into a “Whole House” or “Living Room + Patio” zone, enable them as separate Zones in Roon, then play to them freely. Note that video Chromecast devices cannot be grouped together in this manner. Due to hardware limitations, Chromecast devices cannot be grouped with other, non-Chromecast devices outside of the Google Home app. You can find detailed instructions regarding Chromecast device grouping using the Google Home app on this
Google knowledgebase page.